![]() 6 Based on this consideration and our previous work in cycloaddition reactions, 12 we considered that stable dienecarbamates 12a,d could be well adapted to our goal. 11 In this context, we envisioned that the use of electron-rich diene partners for the DA reaction might be a solution to improve efficiency of this cycloaddition. ![]() However, despite their potential usefulness, the azo-DA reactions have rarely been utilized as click reactions because of the requirement of catalysts or heating. 8 Several catalytic enantioselective cycloadditions using chiral Lewis or Brønsted acid catalysts have been also reported.8, 9 In addition, the easy synthesis of these azodicarbonyl compounds incorporating biological molecules makes them valuable reagents for the bioconjugation. Typical examples of such reactions include: (1) cycloaddition reactions (1,3-dipolar cycloadditions and hetero-Diels-Alder reactions), (2) nucleophilic ring-opening reactions of strained heterocyclic electrophiles (such as epoxides, aziridines and, aziridinium ions), (3) carbonyl chemistry (formation of imines, oxime ethers, hydrazones and amides), (4) additions to carbon-carbon multiple bonds (epoxidation, aziridination, Michael addition), (5) thiol-ene additions and (6) azide-phosphine reaction (Staudinger ligation).1, 1(a), 1(b), 1(c), 1(d), 1(e), 2, 2(a), 2(b), 2(c), 3, 3(a), 3(b), 3(c), 3(d), 3(e), 4, 4(a), 4(b), 5, 5(a), 5(b), 5(c), 5(d), 5(e), 6, 7 Despite the significant advance made in this field over the past decade, there is still a demand for the development of novel click reactions, especially ones requiring no catalyst to complement the existing arsenal.įor many years, stable azodicarboxylates have been recognized as highly reactive dienophiles in the azo-Diels–Alder (azo-DA) reaction (Scheme 1a) and have been broadly used for the synthesis of key intermediates for the preparation of natural and pharmaceutical products (Fig. The starting materials must be readily available, and the reaction should have broad functional group tolerance and scope. ![]() Click chemistry has become a powerful chemical tool in various research areas such as organic chemistry, 1 drug discovery, 2 bioconjugation, 3 radiochemistry, 4 and chemical biology.2(a), 5 As defined by Sharpless, 6 a click reaction proceeds rapidly under mild conditions to produce building blocks with high selectivity, specificity, and yield, without byproducts.
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![]() See 'git -help'.įatal: The remote end hung up unexpectedly I kept getting: git: '/repopath/repo.git' is not a git command. This allowed me to successfully clone and commit, but I could not push to the bare repo on the server. Use the private key you created on the server to clone your repo from (for some reason, the root is the C: drive).Initialized empty Git repository in C:/repopath/repo.git/ Open Git Bash and create a repository anywhere on your PC: $ git -bare init repo.git GITCOREPATH='/cygdrive/c/Program Files (x86)/Git/libexec/git-core' put both keys in the user's CopSSH/home/user/.ssh directory.Īdd the following to the user's CopSSH/home/user/.bashrc file: GITPATH='/cygdrive/c/Program Files (x86)/Git/bin' Create public/private keys using PuTTygen.When creating the CopSSH user, uncheck Password Authentication and check Public Key Authentication so your public/private keys will work.In retrospect, if I had known how time consuming this would be, I might have started out with Mercurial as I read the install on Windows is easier, but I'll have an opinion on that after I work with Git awhile and then try Mercurial.Īfter following Tim Davis' guide and Steve's follow-up, here is what I did: ![]() Plus O'Reilly's Version Control with Git - the Remote Repositories chapter. These other sources helped me figure things out: Git clone using ssh - can't find repository Learn a vcs like I did with rcs and Subversion and The newer msysgit versions might not give youĮxecutable where you choose between the Git There is some duplication here - it works for me, so someone chime in which is the correct place to modify the path. Here's what I added to the bash profile (in CopSsh etc/profile):Įxport PATH="/bin:$syspath:$gitpath:$gitcorepath:$winpath" Gitcorepath='cygdrive/c/Program Files (x86)/Git/libexec/git-core' Gitpath='/cygdrive/c/Program Files (x86)/Git/bin' bashrc (in your CopSsh and Windows home directory): I hope my pain benefits someone else in the future, because this was an arduous process. Like Tim Davis said, this was an arduous and frustrating process, at least for me - I'm not too good with integration of this sort, but I learned alot in the process. With regards to the reference to the Tim Davis page - Setting up a Msysgit Server with copSSH on Windows - I used this to get a Git server running on Windows 7 Home Premium 64.īelow is a postmortem/update of what I learned in addition to his instructions. GitStack is completely free for small teams 1.ġ the basic edition is free for up to 2 users The top of the genuine Git for Windows and is compatible with any GitStack also makes it superĮasy to secure and keep your server up to date. This means that you create a leading edge versioning GitStack is a software that lets you setup your own private Git serverįor Windows. Here is a description from their web site: User and team based repository access managementīrad Kingsley has a nice tutorial for installing and configuring Bonobo Git Server.User friendly web interface for management.Secure and anonymous access to your git repositories.Your IIS and easily manage and connect to your git repositories.īonobo Git Server is a open-source project and you can find the Bonobo Git Server for Windows is a web application you can install on ![]() The company will contact users once it’s being installed in their area. Note: The website states if users already have a ntouch VP, they do not need to apply for the VP2 upgrade. ![]() Both are noted to feature a dazzling design, remarkable clarity, and brilliant technology. The ntouch® VP “has been installed in more deaf homes than all other videophones combined!” The ntouch® VP and VP2 are the company’s popular videophones, but the VP2 is the newest upgrade. In order to use the following products, users must also apply for an SVRS Product and Service Application found here. They combined the “best features with the highest quality SVRS interpreters” so users receive an “unmatched communication experience”. Sorenson Communications has designed the ntouch® suite of products specifically for individuals who are deaf. Additionally, they also offer apps to improve communication on text messages and in person! Keep on reading to learn more. Their videophones are the only videophones designed specifically for those who are deaf. The company’s mission is to provide the “highest quality communication products and services” to individuals who are deaf or hard-of-hearing. They offer a myriad of products for individuals who are deaf such as the ntouch® VP videophone and app, Buzz apps, and more. Sorenson Communications is “the leading provider of Video Relay Service (VRS) for the Deaf”. Written by Laura Medcalf on April 5th, 2017 April 4th, 2017. ![]() It was all part of Kirshner's retroactive history of his experiences with the Monkees where he was the smart producer and they were morons who passed on great songs like "Sugar, Sugar. ![]() What happened is that while Kirshner kept feuding with the Monkees (especially Nesmith), until they outright fired him, he had offered them a song called "Sugar Man" and that evolved over the years into him offering "Sugar, Sugar" and Nesmith freaking out on him and punching a wall. The Archies Sugar, Sugar (1969, Vinyl) - Discogs View credits, reviews, tracks and shop for the 1969 Vinyl release of 'Sugar, Sugar' on Discogs. The writing and the recording and the euphoria of being part of it just excited me."īarry also noted that it was specifically written with very little kids in mind, as that was the target of the song. It reached number one in the US in 1969 and stayed there for four weeks. Everythings Archie 'Sugar, Sugar' 1969 1 22 6 1 1 1 1 1 1 1 'La Dee Doo Down Down' (South Africa and Zimbabwe-only release) 2. It was performed by The Archies, a band formed by a group of fictional teenagers in the television cartoon series The Archie Show. Released in some countries as Sugar Sugar 66 59 25 Jingle Jangle: Released: December 1969 Label: Kirshner Formats: LP, MC, 8-track 125 78 Sunshine: Released: August 1970. There was no time to analyze and to pontificate and to see if it made any sense. 'Sugar, Sugar' is a pop song written by Jeff Barry and Andy Kim. E-Book Overview An examination of political, social and cultural developments in the Soviet Union. And with the magical mind of Jeff Barry, a great record was made. ![]() 'Sugar, Sugar' was one of those songs that I kept humming. Kim recalled, "It wasn't written for anything other than to satisfy a Saturday morning animated show. It is important to note that BMI is not a diagnostic tool and should not be used as the sole basis for determining a person's health. The BMI is a measure of body fat based on height and weight that is commonly used to determine whether a person is underweight, normal weight, overweight, or obese. According to the WHO's division and classification, there are three main BMI levels for men (underweight, normal/healthy, and overweight, as previously indicated).Ī BMI calculator for male (BMI calculator for men) is a tool that allows men to calculate their Body Mass Index (BMI) based on their height and weight. There are numerous official ways to categorize normal BMI for males (BMI calculator for male) because there are so many possibilities available when it comes to building up the various BMI categories for men. This indicates that we shouldn't assume that the healthy BMI for men and women will be the same and that the BMI ranges for men and women will also not be the same. We now know that the BMI formula does not account for gender therefore, why do men require a Body Mass Index calculator? The BMI calculator for men, anthropomorphically speaking, men and women have different bodily traits within adults, even within children and teenagers. Once someone knows how to calculate BMI (BMI calculator India), they can find out where their measurement falls in the following standard weight categories(BMI calculator kg with age) Here, we offer a BMI calculator (BMI calculator India), go over the advantages and disadvantages of BMI calculations (BMI calculator kg with age), and describe some additional techniques that people who were born as females may find helpful for monitoring their health. To use a BMI calculator female (BMI calculator women), women simply need to enter their height and weight, and the calculator will provide an estimate of their BMI. Instead, it should be used in conjunction with other measures, such as waist circumference and body fat percentage, to assess a person's overall health and risk of developing conditions such as obesity, heart disease, and diabetes. It is important to note that the BMI calculator female (BMI calculator women) is not a diagnostic tool and should not be used as the sole basis for determining a person's health. However, because BMI does not explicitly measure body fat, it has certain limits for those who are born with the gender assigned to them.Ī BMI calculator female (BMI calculator women) is a tool that allows women to calculate their Body Mass Index (BMI) based on their height and weight. If your BMI is 30 or more, you can be obese.Ī person's BMI can be used to determine whether they are overweight or underweight. ![]() According to doctors, a woman's BMI should be between 18.5-24.9. However, it makes use of common weight status categories like height weight charts that can assist medical professionals in monitoring weight status across populations and spotting possible problems in specific patients.īased on weight and height, the body mass index (BMI) provides an approximation of the body composition. The physician will provide appropriate advice. Numerous health concerns, including type 2 diabetes, high blood pressure, and cardiovascular issues, can be brought on by carrying too much weight (Try calculating the BMI calculator by age to be sure).Ī too-low weight can raise the risk of anemia, osteoporosis, and starvation. If you want to know how to calculate BMI, then keep reading to find more info. A person's health risks may drastically rise if their BMI is outside of the healthy range. ![]() A person's BMI or body mass index is a screening metric that can show if they are underweight, have a healthy weight, are overweight, or are obese. ![]() However, compression molding is a lower-pressure production method, so the tooling costs are often lower. Injection molding requires a shorter cycle time than compression molding, so it’s often faster and more cost-effective if you need to produce a large number of parts. Injection molding is typically a better choice for more complex parts, while compression molding is a great option for relatively simple designs, including ultra-large basic shapes that cannot be produced using extrusion techniques. Today’s manufacturers frequently use both compression and injection molding but for different types of parts. ![]() In compression molding, molds are closed around the charge, and in injection molding, the charge is injected into a closed mold cavity. ![]() Injection MoldingĬompression molding and injection molding are very similar, but they have one major difference. Release part - Remove the finished piece.Ĭlean part - Resin flash around the edges must be manually cut off or removed, and the part may need to be cleaned before the final assembly.Ĭompression Molding vs. Many manufacturers also use heat during the compression process, which softens the raw materials and can help speed up production. Insert charge - Place the charge in the center of the bottom mold.Ĭompress part - Close the top mold, apply pressure, and wait for your piece to form. If your charge is too big, excess material will seep out of the mold and result in flash that you will need to manually cut off. Prepare charge - Selected the type of material you want to use and determine the proper amount of material. Set up the machine - Depending on the specific machine or device you’re using, this may include cleaning the mold, turning on the heat, and other set-up processes. The step-by-step compression molding process works as follows:Ĭreate molds - Tooling can be produced in a number of ways, including machining, die casting, 3D printing. You can, however, refund any money left over in your account from other payments that have been made. This is because promotional codes are only used for advertising. Can I Request a Refund If I Have Money Left In My Promo Code After I’ve Cancelled My Account?Īdvertisers can’t refund any money that has been left in their promotional code once they cancel their accounts. In other words, if the offer is restricted to USA residents and your address is in Canada, then you’re not eligible for the offer. Your billing address must match the region or country that’s specified in the offer’s details. As an Advertiser, Am I Eligible for Promo Offers in a Different Country? Then you can assess how well your ad worked for you after the promotion has ended. Make your end date 20 days from starting your promo. If your daily campaign budget is $15, then you can calculate the number of days your campaign will run as follows: The best way to avoid spending more money than your promotion is by entering the end date through your campaign settings.įor instance, if your promotional code is “spend $100, and receive $200”, and you want your ad to stop showing after the couple code is finished, all you need to do is calculate the end date by dividing the total coupon value ($100 + $200 = $300) by your campaign’s daily budget. How Can I Stop Spending More Money Than What is Offered In My Google Ads Promo Code? If you’re using a manual payment method, however, then your ads will stop showing as soon as your code has been used up. In this instance, you’ll be charged for any other clicks. If you’re using an automatic payment method, your ad will continue to run, whether or not your code has been used up, and will continue to run until you stop them. The answer depends on the payment method you’re using. Many advertisers wonder if their ads can be used after the promo code has been exhausted. Can Ads Be Used After The Code Has Been Used? If your budget ends without having used up the full amount of credit, the remaining amount will carry over to the next activated budget. Your new budget will then be $300, but you’ll only be charged $200 since the promotion covers the additional $100. While the credit will increase your budget, you’ll only be charged for whatever budget you set initially.įor instance, let’s say you set your budget for $200, and you received a promo of $100. Unused promo credit will roll over to next month. Then, once the account meets the offer requirements, you’ll see the credit appear in your transaction history page. Monthly Invoicing – If you’re using monthly invoicing, you’ll need to enter the promo code after your account is set up for this invoicing system. As the advertiser, you need to add at least $100 into your account before spending the $100 you need to receive the $200 credit. ![]() If you’re using a manual method of payment, you may need to add funds to your account before running your ads.įor example, let’s say the promotion is “Spend $100 get $200”. Then, while your ads are up and you begin accruing costs, your payment credit will decrease. ![]() Manual Payment (Pre-pay) – This system gets you to make a payment before your ads go live. Once the account spends the amount required for the offer, you’ll receive the credit.įor instance, promotions such as “Spend $100 and get $200” requires the advertiser to spend at least $100 to receive the $200 account credit. How your promo codes work is based on what payment method you’re using.Īutomatic Payment (Post-pay) – Once your ads run, Google will automatically charge your method of payment. To understand how long you need to wait before entering a new promo code, read your promotional code’s offer details. While some promo codes can be entered after just earning a previous credit, there’s usually a minimum wait time between credits. If you’ve recently earned a promo credit, your account won’t be eligible for another one. Can I Get Another Google Ads Promo Code After I’ve Used The Last One? To use your promo code hasn’t been used, check with the terms that came with the code to brush up on the details surrounding your offer. Promo codes can only be entered and used once, and advertisers aren’t allowed to share the same promo code with other accounts. Any completed or expired promos can be found on the “Completed Promotions” card, you will see this section once you will consume the code.Ĭan Promo Codes Be Shared With Other Advertisers?.You’ll then see the progress bar for your current codes on your “Active Promotions” card once you have used it. Regardless of the house or window style, Wincore offers a number of window options bound to fit your style and budget preference. Many homeowners prefer the look of casement styles, so they may be willing to pay more for them. Double hung windows tend to cost less than casement windows. Wincore windows price vary according to size and style. Wincore Windows offers a lifetime limited warranty on its replacement windows product lineup. Wincore Windows can be used for both window replacement and new construction purposes. 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